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Synthesis and characterization of Zn(O,OH)S and AgInS2 layers to be used in thin film solar cells

Identifieur interne : 003784 ( Main/Repository ); précédent : 003783; suivant : 003785

Synthesis and characterization of Zn(O,OH)S and AgInS2 layers to be used in thin film solar cells

Auteurs : RBID : Pascal:10-0497382

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English descriptors

Abstract

In this paper AgInS2 and Zn(O,OH)S thin films were synthesized and characterized. AgInS2 layers were grown by co-evaporation from metal precursors in a two-step process, and, Zn(O,OH)S thin films were deposited from chemical bath containing thiourea, zinc acetate, sodium citrate and ammonia. X-ray diffraction measurements indicated that AgInS2 thin films grown with chalcopyrite structure, and the as-grown Zn(O,OH)S thin films were polycrystalline. It was also found that the AgInS2 films presented p-type conductivity, a high absorption coefficient (greater than 104 cm-1) and energy band-gap Eg of about 1.95 eV, Zn(O,OH),S thin films presented Eg of about 3.89 eV. Morphological analysis showed that under this synthesis conditions Zn(O,OH),S thin films coated uniformly the absorber layer. Additionally, the Zn(O,OH)S kinetic growth on AgInS2 layer was studied also. Finally, the results suggest that these layers possibly could be used in one-junction solar cells and/or as top cell in a tandem solar cell.

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<title xml:lang="en" level="a">Synthesis and characterization of Zn(O,OH)S and AgInS
<sub>2</sub>
layers to be used in thin film solar cells</title>
<author>
<name sortKey="Vallejo, W" uniqKey="Vallejo W">W. Vallejo</name>
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<s1>Departamento de Química, Universidad Nacional de Colombia, Cra 30 No 45-03</s1>
<s2>Bagotá</s2>
<s3>COL</s3>
<sZ>1 aut.</sZ>
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<country>Colombie</country>
<wicri:noRegion>Bagotá</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Arredondo, C A" uniqKey="Arredondo C">C. A. Arredondo</name>
<affiliation wicri:level="1">
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<s1>Departamento de Física, Universidad Nacional de Colombia, Cra 30 No 45-03</s1>
<s2>Bogota</s2>
<s3>COL</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Colombie</country>
<wicri:noRegion>Bogota</wicri:noRegion>
</affiliation>
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<author>
<name sortKey="Gordillo, G" uniqKey="Gordillo G">G. Gordillo</name>
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<s1>Departamento de Física, Universidad Nacional de Colombia, Cra 30 No 45-03</s1>
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<s3>COL</s3>
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<sZ>3 aut.</sZ>
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<country>Colombie</country>
<wicri:noRegion>Bogota</wicri:noRegion>
</affiliation>
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<date when="2010">2010</date>
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<term>Absorption coefficient</term>
<term>Buffer layer</term>
<term>Chalcopyrite structure</term>
<term>Chemical bath deposition</term>
<term>Energy gap</term>
<term>Indium sulfide</term>
<term>Kinetics</term>
<term>P type conductivity</term>
<term>Silver sulfide</term>
<term>Sodium</term>
<term>Solar cell</term>
<term>Ternary compound</term>
<term>Thin film</term>
<term>Vaporization</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Couche mince</term>
<term>Cellule solaire</term>
<term>Sodium</term>
<term>Diffraction RX</term>
<term>Structure chalcopyrite</term>
<term>Conductivité type p</term>
<term>Coefficient absorption</term>
<term>Bande interdite</term>
<term>Cinétique</term>
<term>Couche tampon</term>
<term>Vaporisation</term>
<term>Sulfure d'argent</term>
<term>Sulfure d'indium</term>
<term>Composé ternaire</term>
<term>Dépôt bain chimique</term>
<term>Zn(O,OH)S</term>
<term>AgInS2</term>
<term>8460J</term>
<term>6110N</term>
<term>6855J</term>
<term>7820C</term>
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<term>Sodium</term>
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<front>
<div type="abstract" xml:lang="en">In this paper AgInS
<sub>2</sub>
and Zn(O,OH)S thin films were synthesized and characterized. AgInS
<sub>2</sub>
layers were grown by co-evaporation from metal precursors in a two-step process, and, Zn(O,OH)S thin films were deposited from chemical bath containing thiourea, zinc acetate, sodium citrate and ammonia. X-ray diffraction measurements indicated that AgInS
<sub>2</sub>
thin films grown with chalcopyrite structure, and the as-grown Zn(O,OH)S thin films were polycrystalline. It was also found that the AgInS
<sub>2</sub>
films presented p-type conductivity, a high absorption coefficient (greater than 10
<sup>4</sup>
cm
<sup>-1</sup>
) and energy band-gap Eg of about 1.95 eV, Zn(O,OH),S thin films presented Eg of about 3.89 eV. Morphological analysis showed that under this synthesis conditions Zn(O,OH),S thin films coated uniformly the absorber layer. Additionally, the Zn(O,OH)S kinetic growth on AgInS
<sub>2</sub>
layer was studied also. Finally, the results suggest that these layers possibly could be used in one-junction solar cells and/or as top cell in a tandem solar cell.</div>
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<sub>2</sub>
layers to be used in thin film solar cells</s1>
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<s1>VALLEJO (W.)</s1>
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<s1>ARREDONDO (C. A.)</s1>
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<s3>COL</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>Departamento de Física, Universidad Nacional de Colombia, Cra 30 No 45-03</s1>
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<s3>COL</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<fC01 i1="01" l="ENG">
<s0>In this paper AgInS
<sub>2</sub>
and Zn(O,OH)S thin films were synthesized and characterized. AgInS
<sub>2</sub>
layers were grown by co-evaporation from metal precursors in a two-step process, and, Zn(O,OH)S thin films were deposited from chemical bath containing thiourea, zinc acetate, sodium citrate and ammonia. X-ray diffraction measurements indicated that AgInS
<sub>2</sub>
thin films grown with chalcopyrite structure, and the as-grown Zn(O,OH)S thin films were polycrystalline. It was also found that the AgInS
<sub>2</sub>
films presented p-type conductivity, a high absorption coefficient (greater than 10
<sup>4</sup>
cm
<sup>-1</sup>
) and energy band-gap Eg of about 1.95 eV, Zn(O,OH),S thin films presented Eg of about 3.89 eV. Morphological analysis showed that under this synthesis conditions Zn(O,OH),S thin films coated uniformly the absorber layer. Additionally, the Zn(O,OH)S kinetic growth on AgInS
<sub>2</sub>
layer was studied also. Finally, the results suggest that these layers possibly could be used in one-junction solar cells and/or as top cell in a tandem solar cell.</s0>
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<fC02 i1="05" i2="X">
<s0>230</s0>
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<fC03 i1="01" i2="X" l="FRE">
<s0>Couche mince</s0>
<s5>01</s5>
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<fC03 i1="01" i2="X" l="ENG">
<s0>Thin film</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA">
<s0>Capa fina</s0>
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<s5>02</s5>
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<s5>02</s5>
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<s5>02</s5>
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<s0>Sodium</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>Sodium</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Sodio</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
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<s0>Diffraction RX</s0>
<s5>07</s5>
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<s0>X ray diffraction</s0>
<s5>07</s5>
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<s0>Difracción RX</s0>
<s5>07</s5>
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<fC03 i1="05" i2="X" l="FRE">
<s0>Structure chalcopyrite</s0>
<s5>08</s5>
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<s0>Chalcopyrite structure</s0>
<s5>08</s5>
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<s5>08</s5>
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<s5>09</s5>
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<s0>P type conductivity</s0>
<s5>09</s5>
</fC03>
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<s0>Conductividad tipo p</s0>
<s5>09</s5>
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<s0>Coefficient absorption</s0>
<s5>10</s5>
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<fC03 i1="07" i2="X" l="ENG">
<s0>Absorption coefficient</s0>
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</fC03>
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<s0>Coeficiente absorción</s0>
<s5>10</s5>
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<s5>11</s5>
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<s0>Energy gap</s0>
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<s5>12</s5>
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<s0>Kinetics</s0>
<s5>12</s5>
</fC03>
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<s0>Cinética</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Couche tampon</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Buffer layer</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Capa tampón</s0>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Vaporisation</s0>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Vaporization</s0>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Vaporización</s0>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Sulfure d'argent</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Silver sulfide</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Plata sulfuro</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Sulfure d'indium</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Indium sulfide</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Indio sulfuro</s0>
<s5>16</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Composé ternaire</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Ternary compound</s0>
<s5>17</s5>
</fC03>
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<s0>Compuesto ternario</s0>
<s5>17</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Dépôt bain chimique</s0>
<s5>22</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Chemical bath deposition</s0>
<s5>22</s5>
</fC03>
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<s0>Depósito baño químico</s0>
<s5>22</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Zn(O,OH)S</s0>
<s4>INC</s4>
<s5>32</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>AgInS2</s0>
<s4>INC</s4>
<s5>33</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>8460J</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>45</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>6110N</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>6855J</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>7820C</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>48</s5>
</fC03>
<fN21>
<s1>333</s1>
</fN21>
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